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5991-3723EN High-Speed Broadband Spectroscopy Measurements Advance Molecular Research - Application Note c20140930 [6]


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Keysight Technologies
High-Speed Broadband
Spectroscopy Measurements
Advance Molecular Research



       Application Note
Introduction

     Rotational spectroscopy has allowed the identification of hundreds of complex molecules and has
     enabled scientists to better understand the laws of the universe including the origins of life on Earth.

     The rotational spectra of small molecules can be analyzed by optical methods in the infrared
     spectrum, however, the rotational transitions offer better resolution in mixtures and better specificity
     to molecular geometry.

     The Keysight Technologies, Inc. next generation data conversion technologies have enabled the
     development of a new technique called segmented chirped pulse Fourier transform millimeter
     (CP-FTmmW) spectroscopy capable of extending spectroscopic measurements to other wavebands
     (millimeter/sub-millimeter and terahertz) to provide the precise rotational fingerprint of molecules.


     Abstract
     Spectroscopy measures the interaction between a sample and electromagnetic radiation (light).
     Light can be emitted (emission spectroscopy), absorbed (absorption spectroscopy) or scattered by
     a sample. Molecular spectroscopy can be used to determine the composition of a substance since a
     molecule's dynamics are uniquely affected by specific frequencies of light.

     Molecular Rotational Resonance (MRR) spectroscopy, a form of molecular spectroscopy, enables the
     accurate identification of the molecular structure of gas phase molecules based on the change of
     angular momentum when interacting with the light field.

     Recent improvements in electronic instrumentation have enabled the development of a chirped pulse
     Fourier transform millimeter-wave (CP-FTmmW) spectrometer capable of measuring the 260 



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