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2767 Pulse


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                                      A   G R E AT E R       M E A S U R E       O F   C O N F I D E N C E   anisms is the key to understanding channel
                                                                                                             mobility degradation and device reliability
                                                                                                             problems. However, traditional DC testing
                                                                                                             techniques may not accurately characterize
                                                                                                             these mechanisms.

                                                                                                             Limitation of DC Characterization
                                                                                                             Techniques
                                                                                                                 As charges are trapped in the gate dielec-
                                                                                                             tric, the threshold voltage of the transistor
                                                                                                             increases due to the built-in voltage in the
                                                                                                             gate capacitor; therefore, the drain current
                                                                                                             decreases. It appears that charge trapping
                                                                                                             and de-trapping times strongly depend on



Pulsed
                                                                                                             the composition of the gate stacks, i.e., physi-
                                                                                                             cal thickness of the interfacial SiO2 layer and
                                                                                                             high-k film, as well as process techniques


Characterization
                                                                                                             [16-18]. The time scale varies from several
                                                                                                             microseconds to tens of milliseconds [19].
                                                                                                             The de-trapping of the charges is also strong-


of Charge-trapping
                                                                                                             ly gate voltage and polarity dependent.
                                                                                                                 The wide dynamic range of charge trap-
                                                                                                             ping, and the voltage dependent trapping


Behavior in High-k
                                                                                                             and de-trapping, make it very difficult to use
                                                                                                             one type of characterization technique (es-
                                                                                                             pecially a DC technique) to get a complete


Gate Dielectrics
                                                                                                             picture of what is going on inside the stacked
                                                                                                             gate dielectric. For example, commonly used
                                                                                                             methods employ a double sweep in either DC
                                                                                                             Vgs-Id or high frequency C-V measurements.
                                                                                                             These techniques involve ramping gate volt-
Yuegang Zhao, Keithley Instruments, Inc.                                                                     age back and forth while drain current or
                                                                                                             gate capacitance is measured. If hysteresis is
Chadwin D Young, Rino Choi, and Byoung Hun Lee,                                                              seen on the resulting I-V or C-V curves, it is
SEMATECH High-k Material Research                                                                            a clear indication of charge trapping inside
                                                                                                             the gate stacks.
                                                                                                                 The issue with this technique is that the
This article discusses the nature of the                be made thicker than SiO2 while achieving            hysteresis is strongly dependent on measure-
charge trapping and the limitation of DC                the same capacitance. The result is leakage          ment time. The hysteresis measured in the
characterization techniques in quantifying              current that can be lower by as much as sev-         DC I-V test could be different from that in
trappedcharge.Then,itdescribesanultra-                  eral orders of magnitude. However, there are         a C-V test, because the time taken for each
fast pulse I-V technique for characterizing             still technical challenges to overcome, such         measurement may be dramatically different.
the intrinsic ("trap free") performance of              as Vt instability [2-4], carrier channel mobil-      This is illustrated by dual sweep C-V meas-
high-k gate transistors that exhibit the fast           ity degradation [5-9], and long-term device          urements taken at different speeds (Figure
transientchargingeffect(FTCE).                          reliability [10-13].                                 1). Test speed is strongly dependent on in-
                                                            One of the important issues preventing           strumentation and not easily controlled.
Development of High-k Gates for                         implementation of high-k gates is the trap-          Even if it were, there is no model to quan-
Advances CMOS Devices                                   ping of charges in the pre-existing traps            tify how much charge is really trapped in the
    High dielectric constant (high-k) materi-           inside these dielectrics [14-15]. When the           gate during the test; i.e., hysteresis cannot
als, such as hafnium oxide (HfO2), zirconium            transistor is turned on, some of the chan-           quantify the amount of charge trapped, since
oxide (ZrO2), alumina (Al2O3), and their sili-          nel carriers will be accumulated in the gate         a significant portion of the fast transient trap-
cates, have drawn a great deal of attention in          dielectric due to the vertical electrical field,     ping could be lost in the DC measurement.
recent years for potential use as gate dielec-          resulting in a shift of threshold voltage and a          Another method involves DC stress volt-
trics in advanced CMOS processes [1]. With              reduction in drain current. Fully understand-        age to inject charges intentionally into the
high dielectric constants, gate dieletrics can          ing charge-trapping and these related mech-          gate, then the use of C-V or I-V method to



Pulsed Characterization of Charge-trapping Behavior in High-k Gate Dielectrics                                                                    May2006        
             1.40E



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