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                             SIGMA-ALDRICH

                      MATERIAL SAFETY DATA SHEET

                                                Date Printed: 10/08/2004
                                                Date Updated: 04/02/2004
                                                           Version 1.3


Section 1 - Product and Company Information

Product Name                         VANILLIN, 99%
Product Number                       V1104
Brand                                ALDRICH

Company                              Sigma-Aldrich
Street Address                       3050 Spruce Street
City, State, Zip, Country            SAINT LOUIS MO 63103 US
Technical Phone:                     314 771 5765
Emergency Phone:                     414 273 3850 Ext. 5996
Fax:                                 800 325 5052

Section 2 - Composition/Information on Ingredient

Substance Name                            CAS #                 SARA 313
VANILLIN                                  121-33-5              No

Formula          C8H8O3
Synonyms         m-Anisaldehyde, 4-hydroxy- * Benzaldehyde,
                 4-hydroxy-3-methoxy- *
                 p-Hydroxy-m-methoxybenzaldehyde *
                 4-Hydroxy-3-methoxybenzaldehyde * Lioxin *
                 3-Methoxy-4-hydroxybenzaldehyde *
                 Methylprotocatechuic aldehyde *
                 Protocatechualdehyde, methyl- * Vanilla *
                 Vanillaldehyde * Vanillic aldehyde * p-Vanillin *
                 Vanilline * Zimco
RTECS Number:    YW5775000

Section 3 - Hazards Identification

EMERGENCY OVERVIEW
   Harmful.
   Harmful if swallowed.
   Caution: Avoid contact and inhalation.

HMIS RATING
   HEALTH: 1
   FLAMMABILITY: 0
   REACTIVITY: 1

NFPA RATING
   HEALTH: 1
   FLAMMABILITY: 0
   REACTIVITY: 1

For additional information on toxicity, please refer to Section 11.

Section 4 - First Aid Measures

ORAL EXPOSURE
   If swallowed, wash out mouth with water provided person is
   conscious. Call a physician.

INHALATION EXPOSURE
   If inhaled, remove to fresh air. If not breathing give
   artificial respiration. If breathing is difficult, give oxygen.

DERMAL EXPOSURE
   In case of skin contact, flush with copious amounts of water for
   at least 15 minutes. Remove contaminated clothing and shoes.
   Call a physician.

EYE EXPOSURE
   In case of contact with eyes, flush with copious amounts of
   water for at least 15 minutes. Assure adequate flushing by
   separating the eyelids with fingers. Call a physician.

Section 5 - Fire Fighting Measures

FLASH POINT
   N/A

AUTOIGNITION TEMP
   N/A

FLAMMABILITY
   N/A

EXTINGUISHING MEDIA
   Suitable: Water spray. Carbon dioxide, dry chemical powder, or
   appropriate foam.

FIREFIGHTING
   Protective Equipment: Wear self-contained breathing apparatus
   and protective clothing to prevent contact with skin and eyes.
   Specific Hazard(s): Emits toxic fumes under fire conditions.

Section 6 - Accidental Release Measures

PROCEDURE TO BE FOLLOWED IN CASE OF LEAK OR SPILL
   Evacuate area.

PROCEDURE(S) OF PERSONAL PRECAUTION(S)
   Wear self-contained breathing apparatus, rubber boots, and heavy
   rubber gloves.

METHODS FOR CLEANING UP
   Sweep up, place in a bag and hold for waste disposal. Avoid
   raising dust. Ventilate area and wash spill site after material
   pickup is complete.

Section 7 - Handling and Storage

HANDLING
   User Exposure: Do not breathe dust. Avoid contact with eyes,
   skin, and clothing. Avoid prolonged or repeated exposure.

STORAGE
   Suitable: Keep tightly closed.

SPECIAL REQUIREMENTS
   Air, light, and moisture sensitive.



ALDRICH - V1104                www.sigma-aldrich.com          Page    2
Section 8 - Exposure Controls / PPE

ENGINEERING CONTROLS
   Safety shower and eye bath. Mechanical exhaust required.

PERSONAL PROTECTIVE EQUIPMENT
   Respiratory: Government approved respirator.
   Hand: Compatible chemical-resistant gloves.
   Eye: Chemical safety goggles.

GENERAL HYGIENE MEASURES
   Wash thoroughly after handling.

Section 9 - Physical/Chemical Properties

Appearance              Physical State: Solid
                        Color: Faintly yellow

Property                Value                At Temperature or Pressure

Molecular Weight        152.15 AMU
pH                      N/A
BP/BP Range             170 

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